One-pot bio-derived ionic liquid conversion followed by hydrogenolysis reaction for biomass valorization: A promising approach affecting the morphology and quality of lignin of switchgrass and poplar.
Identifieur interne : 000814 ( Main/Exploration ); précédent : 000813; suivant : 000815One-pot bio-derived ionic liquid conversion followed by hydrogenolysis reaction for biomass valorization: A promising approach affecting the morphology and quality of lignin of switchgrass and poplar.
Auteurs : Chiara Francesca Carrozza [Italie] ; Gabriella Papa [États-Unis] ; Attilio Citterio [Italie] ; Roberto Sebastiano [Italie] ; Blake A. Simmons [États-Unis] ; Seema Singh [États-Unis]Source :
- Bioresource technology [ 1873-2976 ] ; 2019.
Descripteurs français
- KwdFr :
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical : Ionic Liquids, Lignin.
- Biomass, Panicum, Wood.
Abstract
The use of bio-derived ionic liquids (e.g., cholinium lysinate) in a one-pot process was evaluated on overall sugar and lignin yields as a function of two model woody and herbaceous feedstocks, switchgrass and poplar, with emphasis on the study of physical and chemical alterations in lignin structure, by performing a detailed mass balance analysis and chemical characterization. Multiple chromatographic and spectroscopic analytical techniques were applied tracking lignin reactivity and partitioning during the ionic liquid one-pot conversion. Depolymerization efficiency of the lignin-rich residue derived from the whole process was investigated as a function of different temperatures and pressures during catalytic hydrogenolysis by Ni(SO)4. This study validates the potential of ionic liquid one pot process as an integrated approach for full exploitation of lignocellulosic feedstocks. The insights gained will contribute to the design of future conversion routes for efficient biomass deconstruction and lignin valorization.
DOI: 10.1016/j.biortech.2019.122214
PubMed: 31605914
Affiliations:
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Simmons</name><affiliation wicri:level="2"><nlm:affiliation>Joint BioEnergy Institute, 5885 Hollis Street, Emeryville, CA, USA; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Joint BioEnergy Institute, 5885 Hollis Street, Emeryville, CA, USA; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA</wicri:regionArea><placeName><region type="state">Californie</region></placeName></affiliation></author><author><name sortKey="Singh, Seema" sort="Singh, Seema" uniqKey="Singh S" first="Seema" last="Singh">Seema Singh</name><affiliation wicri:level="2"><nlm:affiliation>Joint BioEnergy Institute, 5885 Hollis Street, Emeryville, CA, USA; Biological and Engineering Science Center, Sandia National Laboratories, 7011 East Avenue, Livermore, CA, USA. 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Multiple chromatographic and spectroscopic analytical techniques were applied tracking lignin reactivity and partitioning during the ionic liquid one-pot conversion. Depolymerization efficiency of the lignin-rich residue derived from the whole process was investigated as a function of different temperatures and pressures during catalytic hydrogenolysis by Ni(SO)<sub>4</sub>. This study validates the potential of ionic liquid one pot process as an integrated approach for full exploitation of lignocellulosic feedstocks. The insights gained will contribute to the design of future conversion routes for efficient biomass deconstruction and lignin valorization.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" IndexingMethod="Automated" Owner="NLM"><PMID Version="1">31605914</PMID><DateCompleted><Year>2019</Year><Month>11</Month><Day>04</Day></DateCompleted><DateRevised><Year>2019</Year><Month>11</Month><Day>04</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-2976</ISSN><JournalIssue CitedMedium="Internet"><Volume>294</Volume><PubDate><Year>2019</Year><Month>Dec</Month></PubDate></JournalIssue><Title>Bioresource technology</Title><ISOAbbreviation>Bioresour Technol</ISOAbbreviation></Journal><ArticleTitle>One-pot bio-derived ionic liquid conversion followed by hydrogenolysis reaction for biomass valorization: A promising approach affecting the morphology and quality of lignin of switchgrass and poplar.</ArticleTitle><Pagination><MedlinePgn>122214</MedlinePgn></Pagination><ELocationID EIdType="pii" ValidYN="Y">S0960-8524(19)31444-0</ELocationID><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.biortech.2019.122214</ELocationID><Abstract><AbstractText>The use of bio-derived ionic liquids (e.g., cholinium lysinate) in a one-pot process was evaluated on overall sugar and lignin yields as a function of two model woody and herbaceous feedstocks, switchgrass and poplar, with emphasis on the study of physical and chemical alterations in lignin structure, by performing a detailed mass balance analysis and chemical characterization. Multiple chromatographic and spectroscopic analytical techniques were applied tracking lignin reactivity and partitioning during the ionic liquid one-pot conversion. Depolymerization efficiency of the lignin-rich residue derived from the whole process was investigated as a function of different temperatures and pressures during catalytic hydrogenolysis by Ni(SO)<sub>4</sub>. This study validates the potential of ionic liquid one pot process as an integrated approach for full exploitation of lignocellulosic feedstocks. The insights gained will contribute to the design of future conversion routes for efficient biomass deconstruction and lignin valorization.</AbstractText><CopyrightInformation>Published by Elsevier Ltd.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Carrozza</LastName><ForeName>Chiara Francesca</ForeName><Initials>CF</Initials><AffiliationInfo><Affiliation>Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering "Giulio Natta" Milano, IT, Italy.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Papa</LastName><ForeName>Gabriella</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Joint BioEnergy Institute, 5885 Hollis Street, Emeryville, CA, USA; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, USA.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Citterio</LastName><ForeName>Attilio</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering "Giulio Natta" Milano, IT, Italy.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Sebastiano</LastName><ForeName>Roberto</ForeName><Initials>R</Initials><AffiliationInfo><Affiliation>Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering "Giulio Natta" Milano, IT, Italy.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Simmons</LastName><ForeName>Blake A</ForeName><Initials>BA</Initials><AffiliationInfo><Affiliation>Joint BioEnergy Institute, 5885 Hollis Street, Emeryville, CA, USA; Biological Systems and Engineering Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA, USA.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Singh</LastName><ForeName>Seema</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Joint BioEnergy Institute, 5885 Hollis Street, Emeryville, CA, USA; Biological and Engineering Science Center, Sandia National Laboratories, 7011 East Avenue, Livermore, CA, USA. Electronic address: seesing@sandia.gov.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2019</Year><Month>09</Month><Day>29</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Bioresour Technol</MedlineTA><NlmUniqueID>9889523</NlmUniqueID><ISSNLinking>0960-8524</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D052578">Ionic Liquids</NameOfSubstance></Chemical><Chemical><RegistryNumber>9005-53-2</RegistryNumber><NameOfSubstance UI="D008031">Lignin</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D018533" MajorTopicYN="N">Biomass</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D052578" MajorTopicYN="Y">Ionic Liquids</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008031" MajorTopicYN="N">Lignin</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008897" MajorTopicYN="Y">Panicum</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D014934" MajorTopicYN="N">Wood</DescriptorName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Catalytic lignin hydrogenolysis</Keyword><Keyword MajorTopicYN="N">Cholinium ionic liquid</Keyword><Keyword MajorTopicYN="N">Ionic liquid pretreatment</Keyword><Keyword MajorTopicYN="N">Lignin-rich residue</Keyword><Keyword MajorTopicYN="N">Mass balance</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2019</Year><Month>07</Month><Day>25</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2019</Year><Month>09</Month><Day>25</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2019</Year><Month>09</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2019</Year><Month>10</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2019</Year><Month>11</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2019</Year><Month>10</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">31605914</ArticleId><ArticleId IdType="pii">S0960-8524(19)31444-0</ArticleId><ArticleId IdType="doi">10.1016/j.biortech.2019.122214</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Italie</li><li>États-Unis</li></country><region><li>Californie</li></region></list><tree><country name="Italie"><noRegion><name sortKey="Carrozza, Chiara Francesca" sort="Carrozza, Chiara Francesca" uniqKey="Carrozza C" first="Chiara Francesca" last="Carrozza">Chiara Francesca Carrozza</name></noRegion><name sortKey="Citterio, Attilio" sort="Citterio, Attilio" uniqKey="Citterio A" first="Attilio" last="Citterio">Attilio Citterio</name><name sortKey="Sebastiano, Roberto" sort="Sebastiano, Roberto" uniqKey="Sebastiano R" first="Roberto" last="Sebastiano">Roberto Sebastiano</name></country><country name="États-Unis"><region name="Californie"><name sortKey="Papa, Gabriella" sort="Papa, Gabriella" uniqKey="Papa G" first="Gabriella" last="Papa">Gabriella Papa</name></region><name sortKey="Simmons, Blake A" sort="Simmons, Blake A" uniqKey="Simmons B" first="Blake A" last="Simmons">Blake A. 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